Asymmetric hydroformylation of styrene using a rhodium catalyst with BDPP as the chiral ligand

被引：35

作者：

MasdeuBulto, AM ^{[1
]}

Orejon, A ^{[1
]}

Castellanos, A ^{[1
]}

Castillon, S ^{[1
]}

Claver, C ^{[1
]}

机构：

[1] UNIV ROVIRA & VIRGILI,DEPT QUIM,E-43005 TARRAGONA,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 06期

关键词：

D O I：

10.1016/0957-4166(96)00218-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric hydroformylation of styrene is performed using the available rhodium [Rh(mu-OMe)(COD)](2) complex with BDPP as the chiral auxiliary ligand, The enantiomeric excesses observed heavily depend on the excess of diphosphine used and ee's of up to 60 % are achieved. The influence of different P and T conditions is also discussed. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：1829 / 1834

页数：6

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