Sulfone-linked paracyclophanes

被引：9

作者：

Baxter, I

Colquhoun, HM ^{[1
]}

Hodge, P

Kohnke, FH

Williams, DJ

机构：

[1] Univ Salford, Dept Chem, Salford M5 4WT, Lancs, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[3] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 18期

关键词：

D O I：

10.1039/a805549a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of the macrocyclic thioether sulfones (S phi SO(2)phi)(n) (phi = 1,4-phenylene; n = 2 or 3) affords sulfone-linked paracyclophanes (phi SO2)(4) and (phi SO2)(6); single crystal X-ray analysis reveals the tetramer, (phi SO2)(4), to be a near-perfect square box, whilst the hexamer, (phi SO2)(6), adopts a much more irregular conformation; exhaustive oxidation of (S phi SO(2)phi)(4), leads not to the expected octamer, (phi SO2)(8), but to the heptasulfone sulfoxide [(phi SO2)(7)(phi SO)].

引用

页码：1991 / 1992

页数：2

共 8 条

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