Role of interface modification in filled and flame-retarded polymer systems

被引:19
作者
Bertalan, G
Marosi, G
Anna, P
Ravadits, I
Csontos, I
Tóth, A
机构
[1] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1521 Budapest, Hungary
[2] Hungarian Acad Sci, Chem Res Ctr, Res Lab Mat & Environm Chem, H-1025 Budapest, Hungary
关键词
interface modification; reactive surfactants; synergistic additives; intumescent flame retardant; filler; calcium carbonate; glass fibre; reinforcement; polyolefins; polypropylene (PP); PP-polyamide blend; X-ray photoelectron spectroscopy (XPS); scanning electron microscopy (SEM); differential scanning calorimetry (DSC);
D O I
10.1016/S0167-2738(01)00795-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
New reactive surfactants (RS) and synergistic reactive surfactants (SRS), containing reactive groups and longer unsaturated apolar hydrocarbon chains have been synthesised and applied in filled and flame-retarded polymer systems, respectively. These additives are capable of reactions with the polymer matrix and the disperse phase as well. The reaction of these compounds with polyolefins was proven on model system by surface analysis, while their reaction with fillers was demonstrated by DSC. The interface modification in filled/reinforced polymer systems and polymer blends resulted in improved mechanical properties. while in pigmented PE it contributed to higher photostability. Furthermore, the efficiency of intumescent flame retardant additives in polyolefins could be enhanced. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:211 / 215
页数:5
相关论文
共 12 条
[1]  
Beamson G., 1992, ADV MATER, DOI DOI 10.1002/ADMA.19930051035
[2]   Development of organic chemical technologies using computer controlled model-reactor [J].
Csontos, I ;
Marosi, G ;
Faigl, F ;
Ravadits, I ;
Komíves, J .
COMPUTERS & CHEMICAL ENGINEERING, 1999, 23 :S995-S998
[3]  
LAGNER R, 1996, THESIS BUDAPEST
[4]  
Maatoug MA, 2000, MACROMOL MATER ENG, V282, P30, DOI 10.1002/1439-2054(20001001)282:1<30::AID-MAME30>3.0.CO
[5]  
2-9
[6]  
MAROSI G, 1987, COLLOID SURFACE, V23, P185
[7]  
MAROSI G, 1993, J POLYM ENG, V12, P34
[8]  
MAROSI G, 2001, IN PRESS MACROMOL S
[9]  
1999, Patent No. 218016
[10]  
1975, Patent No. 167063