Mild and efficient formation of symmetric biaryls via Pd(II) catalysts and Cu(II) oxidants

被引：27

作者：

Parrish, JP ^{[1
]}

Flanders, VL ^{[1
]}

Floyd, RJ ^{[1
]}

Jung, KW ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 44期

基金：

美国国家卫生研究院;

关键词：

biaryls; catalysis; dienes; diynes; homocoupling;

D O I：

10.1016/S0040-4039(01)01691-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Described herein is a mild and efficient palladium-catalyzed synthesis of symmetric biaryls front organostannanes. This methodology offers products rapidly in very high yields. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：7729 / 7731

页数：3

共 23 条

[1] A GENERAL-METHOD FOR THE COUPLING OF VINYL STANNANES [J].

BEDDOES, RL ;

CHEESERIGHT, T ;

WANG, JY ;

QUAYLE, P .

TETRAHEDRON LETTERS, 1995, 36 (02) :283-286

[2]

BOONS GJ, 1993, TETRAHEDRON LETT, V34, P5649

[3] FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB [J].

DE MEIJERE, A ;

MEYER, FE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) :2379-2411

[4] CATALYST TAILORING FOR PALLADIUM-MEDIATED CROSS COUPLING OF ARYLSTANNANES WITH VINYL TRIFLATES [J].

FARINA, V ;

ROTH, GP .

TETRAHEDRON LETTERS, 1991, 32 (34) :4243-4246

[5] PALLADIUM-CATALYZED COUPLING OF ARYLSTANNANES WITH ORGANIC SULFONATES - A COMPREHENSIVE STUDY [J].

FARINA, V ;

KRISHNAN, B ;

MARSHALL, DR ;

ROTH, GP .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (20) :5434-5444

[6] FORMATION OF 1,3-DIYNES, 1,3-DIENES, AND BIPHENYLS VIA THE COPPER(II) NITRATE MEDIATED COUPLING OF ORGANOTIN COMPOUNDS [J].

GHOSAL, S ;

LUKE, GP ;

KYLER, KS .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (19) :4296-4298

[7] OXIDATIVE COUPLING OF ACETYLENES .2. [J].

HAY, AS .

JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (09) :3320-&

[8] Novel carbon-carbon bond formation through Mizoroki-Heck type reaction of silanols and organotin compounds [J].

Hirabayashi, K ;

Ando, J ;

Kawashima, J ;

Nishihara, Y ;

Mori, A ;

Hiyama, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (06) :1409-1417

[9] Palladium-catalyzed homocoupling of organostannanes [J].

Kang, SK ;

Namkoong, EY ;

Yamaguchi, T .

SYNTHETIC COMMUNICATIONS, 1997, 27 (04) :641-646

[10] Copper- and manganese-catalyzed homocoupling of organostannanes in the presence of iodine [J].

Kang, SK ;

Baik, TG ;

Jiao, XH ;

Lee, YT .

TETRAHEDRON LETTERS, 1999, 40 (12) :2383-2384

← 1 2 3 →