Curvature determination of spinodal interface in a condensed matter system

被引:145
作者
Jinnai, H
Koga, T
Nishikawa, Y
Hashimoto, T
Hyde, ST
机构
[1] KYOTO UNIV, GRAD SCH ENGN, DEPT POLYMER CHEM, KYOTO 60601, JAPAN
[2] AUSTRALIAN NATL UNIV, RES SCH PHYS SCI & ENGN, DEPT MATH APPL, CANBERRA, ACT 0200, AUSTRALIA
关键词
D O I
10.1103/PhysRevLett.78.2248
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Laser scanning confocal microscopy has been used to study the time evolution of a three dimensional spatially bicontinuous structure of a phase-separated polymer blend undergoing the late stage of spinodal decomposition, as a model example of condensed matter systems. Bath the mean and Gaussian curvatures of the interface between two coexisting phases have been directly measured for the first time from the reconstructed 3D image. The Gaussian curvature is negative, clearly demonstrating that the interface of the bicontinuous structure is anticlastic, while the mean curvature is close to zero. Self-similar growth of the structure is inferred from the time evolution of the average radius of curvature of the interface.
引用
收藏
页码:2248 / 2251
页数:4
相关论文
共 30 条
[1]   SMALL-ANGLE X-RAY-SCATTERING FROM TERNARY MICROEMULSIONS DETERMINES MICROSTRUCTURE [J].
BARNES, IS ;
HYDE, ST ;
NINHAM, BW ;
DERIAN, PJ ;
DRIFFORD, M ;
ZEMB, TN .
JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (08) :2286-2293
[2]   SPINODAL DECOMPOSITION OF A SYMMETRIC CRITICAL MIXTURE OF DEUTERATED AND PROTONATED POLYMER [J].
BATES, FS ;
WILTZIUS, P .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (05) :3258-3274
[4]  
BINDER K, 1974, PHYS REV LETT, V33, P1006, DOI 10.1103/PhysRevLett.33.1006
[5]   STRUCTURAL EVOLUTION WITHIN THE ONE-PHASE REGION OF A 3-COMPONENT MICROEMULSION SYSTEM - WATER-N-DECANE-SODIUM-BIS-ETHYLHEXYLSULFOSUCCINATE (AOT) [J].
CHEN, SH ;
CHANG, SL ;
STREY, R .
JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (03) :1907-1918
[6]   Measurement of the Gaussian curvature of the surfactant film in an isometric bicontinuous one-phase microemulsion [J].
Chen, SH ;
Lee, DD ;
Kimishima, K ;
Jinnai, H ;
Hashimoto, T .
PHYSICAL REVIEW E, 1996, 54 (06) :6526-6531
[7]  
Gunton J.D., 1983, Phase Transitiona and Critical Phemomena, P269
[8]   BICONTINUOUS MICRODOMAIN MORPHOLOGY OF BLOCK COPOLYMERS .1. TETRAPOD-NETWORK STRUCTURE OF POLYSTYRENE POLYISOPRENE DIBLOCK POLYMERS [J].
HASEGAWA, H ;
TANAKA, H ;
YAMASAKI, K ;
HASHIMOTO, T .
MACROMOLECULES, 1987, 20 (07) :1651-1662
[9]  
HASHIMOT T, 1993, STRUCTURE PROPERTIES, V12
[10]   SCATTERING STUDIES OF SELF-ASSEMBLING PROCESSES OF POLYMER BLENDS IN SPINODAL DECOMPOSITION [J].
HASHIMOTO, T ;
TAKENAKA, M ;
JINNAI, H .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 (pt 5) :457-466