Novel bi- and tridentate phosphane and thioether ligands derived from chiral α-hydroxy acids

被引:23
作者
Christoffers, J [1 ]
Rissler, U [1 ]
机构
[1] Tech Univ Berlin, Inst Organ Chem, Sekretariat C3, D-10623 Berlin, Germany
关键词
D O I
10.1016/S0957-4166(99)00103-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Novel bi- and tridentate ligands with phosphane and thioether moieties have been prepared in enantiomerically pure form in good to excellent yields by substitution reactions with phosphorus and sulfur nucleophiles of easily available tosylates derived from natural chiral cx-hydroxy acids. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:1207 / 1215
页数:9
相关论文
共 19 条
[1]  
Brunner H., 1984, Angew. Chem, V96, P305
[2]   Novel synthesis of chiral, enantiomerically pure thiodiglycols and diglycols [J].
Christoffers, J ;
Rössler, U .
TETRAHEDRON-ASYMMETRY, 1998, 9 (13) :2349-2357
[3]  
Christoffers J, 1997, LIEBIGS ANN-RECL, P1353
[4]  
Christoffers J, 1998, EUR J ORG CHEM, V1998, P1259
[5]   ASYMMETRIC REDUCTION OF CARBONYL-COMPOUNDS BY YEAST .4. PREPARATION OF OPTICALLY-ACTIVE BETA-HYDROXY SULFIDES, SULFOXIDES AND SULFONES [J].
CRUMBIE, RL ;
DEOL, BS ;
NEMORIN, JE ;
RIDLEY, DD .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1978, 31 (09) :1965-1980
[6]   COPPER(II) IN ORGANIC-SYNTHESIS .11. EVALUATION DF THE LIGAND ARCHITECTURE ON THE EFFICIENCY OF A COPPER(II) CATALYST FOR ENANTIOSELECTIVE MICHAEL REACTIONS [J].
DESIMONI, G ;
DUSI, G ;
FAITA, G ;
QUADRELLI, P ;
RIGHETTI, P .
TETRAHEDRON, 1995, 51 (14) :4131-4144
[7]  
End N, 1998, CHEM-EUR J, V4, P818, DOI 10.1002/(SICI)1521-3765(19980515)4:5<818::AID-CHEM818>3.0.CO
[8]  
2-#
[9]  
IQBAL J, 1990, TETRAHEDRON, V46, P6423
[10]   ALKALI-PHOSPHORVERBINDUNGEN UND IHR REAKTIVES VERHALTEN .36. REAKTIONEN DER ALKALIPHOSPHIDE MIT CYCLISCHEN ATHERN [J].
ISSLEIB, K ;
ROLOFF, HR .
CHEMISCHE BERICHTE-RECUEIL, 1965, 98 (07) :2091-&