A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal-Organic Frameworks

被引：401

作者：

Guillerm, V. ^{[1
]}

Ragon, F. ^{[1
]}

Dan-Hardi, M. ^{[1
]}

Devic, T. ^{[1
]}

Vishnuvarthan, M. ^{[2
]}

Campo, B. ^{[2
]}

Vimont, A. ^{[2
]}

Clet, G. ^{[2
]}

Yang, Q. ^{[3
,4
]}

Maurin, G. ^{[3
]}

Ferey, G. ^{[1
]}

Vittadini, A. ^{[5
,6
]}

Gross, S. ^{[5
,6
]}

Serre, Christian ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France

[2] Univ Caen, Lab Catalyse & Spectrochim, Ensicaen, CNRS, F-14050 Caen, France

[3] Univ Montpellier 2, Inst Charles Gerhardt, UMR CNRS 5253, ENSCM CNRS UMI UMII, F-34095 Montpellier 05, France

[4] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China

[5] Univ Padua, ISTM CNR, Dipartimento Sci Chim, I-35131 Padua, Italy

[6] Univ Padua, INSTM, UdR Padova, I-35131 Padua, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 37期

关键词：

infrared spectroscopy; metal-organic framework; modeling studies; stability; zirconium; CRYSTAL-STRUCTURE; SURFACE-AREAS; CHAINS; WATER; ADSORPTION; ALUMINUM; SOLIDS; UIO-66;

D O I：

10.1002/anie.201204806

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one-dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9267 / 9271

页数：5

共 52 条

[1]

[Anonymous], 2012, CHEM REV

[2]

[Anonymous], 2009, Chem. Soc. Rev, V38, P1201, DOI DOI 10.1039/B906666G

[3]

[Anonymous], 2008, ANGEW CHEM INT EDIT, V47, P6766

[4] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part II. Analysis of the Inorganic Crystal Structure Database (ICSD) [J].

Baburin, IA ;

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2452-2474

[5] Evaluation of the BET Method for Determining Surface Areas of MOFs and Zeolites that Contain Ultra-Micropores [J].

Bae, Youn-Sang ;

Yazaydin, A. Oezguer ;

Snurr, Randall Q. .

LANGMUIR, 2010, 26 (08) :5475-5483

[6] Role and Effective Treatment of Dispersive Forces in Materials: Polyethylene and Graphite Crystals as Test Cases [J].

Barone, Vincenzo ;

Casarin, Maurizio ;

Forrer, Daniel ;

Pavone, Michele ;

Sambi, Mauro ;

Vittadini, Andrea .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 2009, 30 (06) :934-939

[7]

Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO

[8]

2-Y

[9]

Barthelet K., 2002, ANGEW CHEM, V114, P291, DOI [DOI 10.1002/1521-3757(20020118)114:2<291:AID-ANGE291>3.0.CO

[10]

2-I, DOI 10.1002/1521-3757(20020118)114:2<291::AID-ANGE291>3.0.CO

← 1 2 3 4 5 6 →