Supramolecular self-assembled nanowires by the aggregation of a protoporphyrin derivative in low-polarity solvents

被引：15

作者：

Bhosale, Sheshanath V. ^{[1
]}

Kalyankar, Mohan B. ^{[2
]}

Nalage, Santosh V. ^{[2
]}

Bhosale, Sidhanath V. ^{[2
]}

Lalander, Cecilia H. ^{[1
]}

Langford, Steven J. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] N Maharashtra Univ, Dept Organ Chem, Jalgaon 425001, Maharashtra, India

来源：

SUPRAMOLECULAR CHEMISTRY | 2011年 / 23卷 / 08期

基金：

澳大利亚研究理事会;

关键词：

protoporphyrin IX; supramolecular chemistry; nanowires; AFM; TEM; PORPHYRIN; COOPERATIVITY; ARCHITECTURES; BEHAVIOR; CRYSTAL; COMPLEX; EXCITON; ARRAYS; IX;

D O I：

10.1080/10610278.2011.575467

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The self-assembly of a simple tetraalkyl-substituted protoporphyrin derivative into fibril wire-like nanostructures from CHCl3/cyclohexane solvent mixes is explored. The protoporphyrin IX derivative is synthesised in two efficient steps by amidation of the two propylenic acid groups followed by a cross metathesis of the vinyl groups using Grubbs' second-generation catalyst. The self-assembly of the functionalised protoporphyrin is sensitive to solvent and under favourable conditions forms 'nanowires' of micrometre length. The nanowires were characterised by absorption and fluorescence spectroscopy, transmission electron microscopy and atomic force microscopy.

引用

页码：563 / 569

页数：7

共 38 条

[1]

Discrete Cyclic Porphyrin Arrays as Artificial Light-Harvesting Antenna [J].

Aratani, Naoki ;

Kim, Dongho ;

Osuka, Atsuhiro .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (12) :1922-1934

[2]

Tailoring porphyrins and chlorins for self-assembly in biomimetic artificial antenna systems [J].

Balaban, TS .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :612-623

[3]

Balaban TS, 2000, EUR J ORG CHEM, V2000, P4047

[4]

RETRACTED: Self-Assembly of Protoporphyrin IX-TEG Derivatives into Tunable Nanoscaled Spherical Structures (Retracted Article) [J].

Bhosale, Sheshanath V. ;

Bhosale, Sidhanath V. ;

Kalyankar, Mohan B. ;

Langford, Steven J. ;

Lalander, Ceilica H. .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2010, 63 (09) :1326-1329

[5]

Solvophobic control of core-substituted naphthalene diimide nanostructures [J].

Bhosale, Sheshanath V. ;

Jani, Chintan ;

Lalander, Cecilia H. ;

Langford, Steven J. .

CHEMICAL COMMUNICATIONS, 2010, 46 (06) :973-975

[6]

Synthesis and Supramolecular Properties of a Novel Octaphosphonate Porphyrin [J].

Bhosale, Sheshanath V. ;

Kalyankar, Mohan B. ;

Langford, Steven J. ;

Bhosale, Sidhanath V. ;

Oliver, Ruth F. .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (24) :4128-4134

[7]

BINDIG U, 1995, NEW J CHEM, V19, P427

[8]

Cooperativity in the self-assembly of porphyrin ladders [J].

Camara-Campos, A ;

Hunter, CA ;

Tomas, S .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (09) :3034-3038

[9]

The first asymmetrically β-polysubstituted porphyrin-based hexagonal columnar liquid crystal [J].

Castella, M ;

López-Calahorra, F ;

Velasco, D ;

Finkelmann, H .

CHEMICAL COMMUNICATIONS, 2002, (20) :2348-2349

[10]

Thin-Film Formation of Imidazolium-Based Conjugated Polydiacetylenes and Their Application for Sensing Anionic Surfactants [J].

Chen, Xiaoqiang ;

Kang, Sunwoo ;

Kim, Min Jung ;

Kim, Joohee ;

Kim, Youn Sang ;

Kim, Heejin ;

Chi, Bo ;

Kim, Sung-Jin ;

Lee, Jin Yong ;

Yoon, Juyoung .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (08) :1422-1425

← 1 2 3 4 →