Temperature-dependent conductivity of Emim+ (Emim+=1-ethyl-3-methyl imidazolium) confined in channels of a metal-organic framework

被引：76

作者：

Chen, Wen-Xian

Xu, Hao-Ran

Zhuang, Gui-Lin

Long, La-Sheng ^{[1
]}

Huang, Rong-Bin

Zheng, Lan-Sun

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 43期

关键词：

IONOTHERMAL SYNTHESIS; IONIC LIQUIDS; PROTON CONDUCTION; MOLECULES; TEMPLATE; SOLVENTS;

D O I：

10.1039/c1cc14702a

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A 3D metal-organic framework, featuring three kinds of cation channels, was obtained through an ionothermal reaction. Investigation on its temperature-dependent conductivity indicates the contribution of order and disorder of the Emim(+) (Emim(+) = 1-ethyl-3-methyl imidazolium bromide) in the channel to its conductivity.

引用

页码：11933 / 11935

页数：3

共 39 条

[1]

Akutagawa T, 2009, NAT MATER, V8, P342, DOI [10.1038/NMAT2377, 10.1038/nmat2377]

[2]

[Anonymous], 2004, DIELECTRIC PHENOMENA

[3]

Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]

[4]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO