Localized Pd overgrowth on cubic Pt nanocrystals for enhanced electrocatalytic oxidation of formic acid

被引：377

作者：

Lee, Hyunjoo ^{[1
,2
,3
]}

Habas, Susan E. ^{[1
,2
]}

Somorjai, Gabor A. ^{[1
,2
]}

Yang, Peidong ^{[1
,2
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Lawrence Berkeley Natl Lab, Div Sci Mat, Berkeley, CA 94720 USA

[3] Yonsei Univ, Dept Chem Engn, Seoul 120749, South Korea

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 16期

关键词：

D O I：

10.1021/ja800656y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Binary Pt/Pd nanoparticles were synthesized by localized overgrowth of Pd on cubic Pt seeds for the investigation of electrocatalytic formic acid oxidation. The binary particles exhibited much less self-poisoning and a lower activation energy relative to Pt nanocubes, consistent with the single crystal study.

引用

页码：5406 / +

页数：3

共 18 条

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