Preparation and electrochemical behaviors of platinum nanocluster catalysts deposited on plasma-treated carbon nanotube supports

被引：9

作者：

Kim, Seok ^{[3
]}

Jung, Yongju ^{[2
]}

Park, Soo-Jin ^{[1
]}

机构：

[1] Inha Univ, Dept Chem, Inchon 402751, South Korea

[2] Korea Atom Energy Res Inst, Nucl Chem Res Div, Taejon 305600, South Korea

[3] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2008年 / 313卷

关键词：

nanoclusters; electrochemistry; carbon nanotubes; catalysts; ELECTRODE;

D O I：

10.1016/j.colsurfa.2007.04.091

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface characteristics of plasma-treated carbon nanotubes (CNTs) were determined by acid-base value measurements using Boehm's titration method. The electrochemical activities of the catalyst electrodes were analyzed by linear sweep voltammetry (LSV) experiments. Plasma treatment on the CNTs at 300 W intensity brought the novel free radicals on the carbon surfaces. X-ray photoelectron spectroscopy (XPS) results for above CNTs-supported platinum catalysts showed that the highest Pt loading efficiency and the highest composition of metal oxidation state when the treatment time was 30 s. Accordingly, the above catalysts exhibited the best electroactivity among the samples. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：189 / 192

页数：4

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