Efficient intramolecular hydroamination of unactivated alkenes catalysed by butyllithium

被引：65

作者：

Ates, A ^{[1
]}

Quinet, C ^{[1
]}

机构：

[1] Catholic Univ Louvain, Dept Chim, Unite Chim Organ & Med, B-1348 Louvain, Belgium

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 09期

关键词：

alkenes; amination; cyclization; lithium;

D O I：

10.1002/ejoc.200300058

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this communication, we wish to report some preliminary results demonstrating, for the first time, that intramolecular hydroamination of unactivated alkenes can be performed efficiently using small quantities of nBuLi as the pre-catalyst. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003

引用

页码：1623 / 1626

页数：4

共 52 条

[1] PALLADIUM-PROMOTED ADDITION OF AMINES TO ISOLATED DOUBLE-BONDS
AKERMARK, B
BACKVALL, JE
HEGEDUS, LS
ZETTERBE.K
SIIRALAH.K
SJOBERG, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 72 (01) : 127 - 138
[2] PLATINUM-PROMOTED CYCLIZATION REACTIONS OF AMINO-OLEFINS .1. CYCLIZATION OF 4-AMINOPENTENE AND RELATED COMPOUNDS
AMBUEHL, J
PREGOSIN, PS
VENANZI, LM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (01) : 329 - 335
[3] PLATINUM-PROMOTED CYCLIZATION REACTIONS OF AMINO OLEFINS .2. REGIOSELECTIVITY AND STEREOSELECTIVITY IN THE CYCLIZATION REACTIONS OF C-METHYL SUBSTITUTED PENT-4-ENYLAMINES
AMBUEHL, J
PREGOSIN, PS
VENANZI, LM
CONSIGLIO, G
BACHECHI, F
ZAMBONELLI, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 181 (01) : 255 - 269
[4] PLATINUM-PROMOTED CYCLIZATION OF 4-PENTENYLAMINE
AMBUHL, J
PREGOSIN, PS
VENANZI, LM
UGHETTO, G
ZAMBONELLI, L
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (05): : 369 - 369
[5] ANIONIC TELOMERIZATIONS OF STYRENE WITH BUTYLAMINES
ASAHARA, T
SENO, M
TANAKA, S
DEN, N
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1969, 42 (07) : 1996 - +
[6] Advances and adventures in amination reactions of olefins and alkynes
Beller, M
Breindl, C
Eichberger, M
Hartung, CG
Seayad, J
Thiel, OR
Tillack, A
Trauthwein, H
[J]. SYNLETT, 2002, (10) : 1579 - 1594
[7] Beller M, 1999, CHEM-EUR J, V5, P1306, DOI 10.1002/(SICI)1521-3765(19990401)5:4<1306::AID-CHEM1306>3.3.CO
[8] 2-W
[9] Anti-Markovnikov functionalization of olefins: Rhodium-catalyzed oxidative aminations of styrenes
Beller, M
Eichberger, M
Trauthwein, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (20): : 2225 - 2227
[10] Beller M, 1998, ANGEW CHEM INT EDIT, V37, P3389, DOI 10.1002/(SICI)1521-3773(19981231)37:24<3389::AID-ANIE3389>3.0.CO

← 1 2 3 4 5 6 →