The role of potassium and hydrogen ions in the Prussian Blue ⇆ Everitt's salt process.

被引：38

作者：

Garcia-Jareno, J ^{[1
]}

Sanmatias, A ^{[1
]}

Navarro-Laboulais, J ^{[1
]}

Vicente, F ^{[1
]}

机构：

[1] Univ Valencia, Fac Quim, Dept Quim Fis, Burjassot 46100, Spain

来源：

ELECTROCHIMICA ACTA | 1998年 / 44卷 / 2-3期

关键词：

Prussian Blue films; voltammetric curves; temperature dependence; entropy change; countercations;

D O I：

10.1016/S0013-4686(98)00072-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Cyclic voltammetry experiments have proved very useful in;he :knowledge and understanding of the role of the potassium and hydrogen ions during the Prussian Blue reversible arrow Everitt's Salt process. While potassium ions act as a stoichiometric reactant, the hydrogen ions play a very important role in the kinetics of the electron-hopping process. The entropy change for the reaction PB reversible arrow ES has proved to be dependent on the degree of crystallinity of the him, indicating that this entropy change is related to the fixation of inner counterions on the crystal structure of the films. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：395 / 405

页数：11

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