Self-assembled titanium-based hybrids with cyclopentadienyl-titanium network bonding

被引:4
作者
Ahmad, Sana [1 ]
Jousseaume, Bernard [1 ]
Servant, Laurent [1 ]
Toupance, Thierry [1 ]
Zakri, Cecile [2 ]
机构
[1] Univ Bordeaux, Inst Mol Sci, CNRS, UMR 5255, F-33405 Talence, France
[2] Ctr Rech Paul Pascal, UPR 8641, F-33600 Pessac, France
关键词
PERIODIC MESOPOROUS ORGANOSILICAS; OLEFIN POLYMERIZATION; CRYSTAL-STRUCTURES; MOLECULAR-SCALE; COMPLEXES; SILICA; ORGANIZATION; HIERARCHY; SPECTRA; WALLS;
D O I
10.1039/c1cc10682a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Unprecedented stable hybrid materials with cyclopentadienyl-titanium bonds have been obtained from the hydrolysis of suitable precursors. Their inorganic network is not fully condensed and they show variable short-range self-organizations, the type of which depends on the shape of the ligands.
引用
收藏
页码:5001 / 5003
页数:3
相关论文
共 45 条
[1]   Linear or cross-shaped di(cyclopentadienyltitanium) compounds with aryl or heteroaryl spacers [J].
Ahmad, Sana ;
Dey, Suvendu Sekhar ;
Jousseaume, Bernard ;
Toupance, Thierry .
DALTON TRANSACTIONS, 2011, 40 (02) :457-462
[2]   Periodic mesoporous organosilicas with organic groups inside the channel walls [J].
Asefa, T ;
MacLachlan, MJ ;
Coombs, N ;
Ozin, GA .
NATURE, 1999, 402 (6764) :867-871
[3]   An efficient, practical and cost-effective polymer-supported catalyst for the transestereification of methyl methacrylate by 1-butanol [J].
Baquey, Gaelle ;
Alves, Marie-Helene ;
Graullier, Magalie ;
Riondel, Alain ;
Paul, Jean-Michel ;
Birot, Marc ;
Deleuze, Herve .
GREEN CHEMISTRY, 2009, 11 (06) :868-872
[4]   Vibrational spectra and structure of the cyclopentadienyl- anion (Cp-), the pentamethylcyclopentadienyl-anion (Cp*-) and of alkali metal cyclopentadienyls CpM and Cp*M (M = Li, Na, K) [J].
Bencze, É ;
Lokshin, BV ;
Mink, J ;
Herrmann, WA ;
Kühn, FE .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 627 (01) :55-66
[5]   Preparation and characterization of (C5Me4Ph)TiCl3, the oxochloride complexes [(C5Me4Ph)TiCl2](2)(mu-O) and [(C5Me4Ph)TiCl(mu-O)](3) and the oxo-complex [(C5Me4Ph)Ti](4)(mu-O)(6). The X-ray crystal structures of [(C5Me4Ph)TiCl2](2)(mu-O) and [(C5Me4Ph)Ti](4)(mu-O)(6) [J].
Bjorgvinsson, M ;
Halldorsson, S ;
Arnason, I ;
Magull, J ;
Fenske, D .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 544 (02) :207-215
[6]   HYDROLYTIC STUDIES ON (ETA-5-C5ME5)TIME3 - X-RAY STRUCTURE OF [(ETA-5-C5ME5)TIME(MU-O)]3 CONTAINING A TI3O3 RING [J].
BLANCO, SG ;
SAL, MPG ;
CARRERAS, SM ;
MENA, M ;
ROYO, P ;
SERRANO, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (21) :1572-1573
[7]  
Boury B, 1999, ANGEW CHEM INT EDIT, V38, P3172, DOI 10.1002/(SICI)1521-3773(19991102)38:21<3172::AID-ANIE3172>3.0.CO
[8]  
2-3
[9]  
Boury B, 2001, ANGEW CHEM INT EDIT, V40, P2853, DOI 10.1002/1521-3773(20010803)40:15<2853::AID-ANIE2853>3.0.CO
[10]  
2-J