Studies on solvation of lithium ions in organic electrolyte solutions by electrospray ionization-mass spectroscopy

被引：56

作者：

Fukushima, T

Matsuda, Y

Hashimoto, H

Arakawa, R

机构：

[1] Kansai Univ, Fac Engn, Dept Appl Chem, Osaka 5648680, Japan

[2] Kansai Univ, High Technol Res Ctr, Osaka 5648680, Japan

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2001年 / 4卷 / 08期

关键词：

D O I：

10.1149/1.1383428

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 [应用化学];

摘要：

Solvation of lithium ions in organic electrolyte solutions, ethylene carbonate (EC), propylene carbonate (PC), and gamma -butyrolactone (GBL) containing LiClO4, for lithium batteries was studied by electrospray ionization-mass spectroscopy (ESI-MS). The mass spectrograms showed that a lithium ion solvated with two or three solvent molecules. (C) 2001 The Electrochemical Society.

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页码：A127 / A128

页数：2

相关论文

共 9 条

[1]

ELECTROSPRAY IONIZATION FOR MASS-SPECTROMETRY OF LARGE BIOMOLECULES [J].

FENN, JB ;

MANN, M ;

MENG, CK ;

WONG, SF ;

WHITEHOUSE, CM .

SCIENCE, 1989, 246 (4926) :64-71

[2]

RAMAN INTENSITY STUDY OF LOCAL-STRUCTURE IN NON-AQUEOUS ELECTROLYTE-SOLUTIONS .2. CATION SOLVENT INTERACTION IN MIXED-SOLVENT SYSTEMS AND SELECTIVE SOLVATION [J].

HYODO, SA ;

OKABAYASHI, K .

ELECTROCHIMICA ACTA, 1989, 34 (11) :1557-1561

[3]

RAMAN INTENSITY STUDY OF LOCAL-STRUCTURE IN NON-AQUEOUS ELECTROLYTE-SOLUTIONS .1. CATION-SOLVENT INTERACTION IN LICLO4/ETHYLENE CARBONATE [J].

HYODO, SA ;

OKABAYASHI, K .

ELECTROCHIMICA ACTA, 1989, 34 (11) :1551-1556

[4]

Raman spectra and transport properties of lithium perchlorate in ethylene carbonate based binary solvent systems for lithium batteries [J].

Klassen, B ;

Aroca, R ;

Nazri, M ;

Nazri, GA .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (24) :4795-4801

[5]

GAS-PHASE CONFORMATIONS OF LI+, NA+, K+, AND CS+ COMPLEXED WITH 18-CROWN-6 [J].

LEE, S ;

WYTTENBACH, T ;

VON HELDEN, G ;

BOWERS, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (40) :10159-10160

[6]

BEHAVIOR OF SOME IONS IN MIXED ORGANIC ELECTROLYTES OF HIGH-ENERGY DENSITY BATTERIES [J].

MATSUDA, Y ;

NAKASHIMA, H ;

MORITA, M ;

TAKASU, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (12) :2552-2556

[7]

A Raman spectroscopic study of organic electrolyte solutions based on binary solvent systems of ethylene carbonate with low viscosity solvents which dissolve different lithium salts [J].

Morita, M ;

Asai, Y ;

Yoshimoto, N ;

Ishikawa, M .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (23) :3451-3456

[8]

Controlled synthesis of transition-metal ion complex solvent clusters by electrospray [J].

Spence, TG ;

Burns, TD ;

Posey, LA .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (02) :139-144

[9]

Polarizability and inductive effect contributions to solvent-cation binding observed in electrospray ionization mass spectrometry [J].

Striegel, AM ;

Piotrowiak, P ;

Boué, SM ;

Cole, RB .

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 1999, 10 (03) :254-260