Photoinduced water oxidation by polymeric iron cyanide complex

被引：4

作者：

Abe, T ^{[1
]}

Shiroishi, H ^{[1
]}

Kinoshita, K ^{[1
]}

Kaneko, M ^{[1
]}

机构：

[1] Ibaraki Univ, Fac Sci, Mito, Ibaraki 310, Japan

来源：

MACROMOLECULAR SYMPOSIA | 1998年 / 131卷

关键词：

D O I：

10.1002/masy.19981310111

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

It was found that photoelectrochemical water oxidation takes place at a polynuclear iron-cyanide complex-coated electrode called Berlin Brown (BB : Fe-4(III)[Fe-III(CN)(6)](3)(3-) 3X(-)). The electrode-coated BE showed electrocatalytic activity for water oxidation to produce O-2 not only in the dark but also under Illumination to result in photoinduced water oxidation. The amount of the photoelectrochemically produced O-2 increased with the thickness of the BE film. indicating that the BE works as a bulk catalyst.

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页码：81 / 86

页数：6

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