Polyhedral boranes with exo multiple bonds: Three-dimensional inorganic analogues of quinones

被引：8

作者：

Balakrishnarajan, MM ^{[1
]}

Hoffmann, R ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 32期

关键词：

ab initio calculations; aromaticity; boranes; Jahn-Teller distortion; multiple bonds;

D O I：

10.1002/anie.200351821

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three dimensional aromaticity: Polyhedral boranes with para-O, -N H, -S substituents should exhibit cylindrical π bonding on oxidation (see picture), with structural and reactivity consequences similar to benzoquinones.

引用

页码：3777 / 3781

页数：5

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