Rapid and efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by manganese(III) Schiff base complexes

被引：67

作者：

Mirkhani, V ^{[1
]}

Tangestaninejad, S

Moghadam, M

Moghbel, M

机构：

[1] Isfahan Univ, Dept Chem, Esfahan 8174673441, Iran

[2] Yasouj Univ, Dept Chem, Yasouj 75914353, Iran

来源：

BIOORGANIC & MEDICINAL CHEMISTRY | 2004年 / 12卷 / 05期

关键词：

biomimetic oxidation; Schiff base; oxidative decarboxylation;

D O I：

10.1016/j.bmc.2003.12.025

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Rapid and efficient oxidative decarboxylatoin of alpha-aryl carboxylic acids was observed. In the chemical system containing Mn(III)-salophen complex as catalyst, carboxylic acids are converted efficiently to the corresponding carbonyl derivatives with sodium periodate. The ability of various Schiff base complexes in the oxidative decarboxylation of carboxylic acids was also investigated. (C) 2004 Elsevier Ltd. All rights reserved.

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页码：903 / 906

页数：4

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