In flagrante metallo-cyclophane self-assembly?

被引：7

作者：

Cragg, PJ

Heirtzler, FR

Howard, MJ

Prokes, I

Weyhermüller, T

机构：

[1] Univ Brighton, Sch Pharm & Biomol Sci, Brighton BN2 4GJ, E Sussex, England

[2] Univ Kent, Sch Phys Sci, Canterbury CT2 7NH, Kent, England

[3] Univ Kent, Res Sch Biosci, Canterbury CT2 7NJ, Kent, England

[4] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England

[5] Max Planck Inst Bioanorgan Chem, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 03期

关键词：

D O I：

10.1039/b310558j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dimeric self-assembly of an alkyl-substituted pyrazine-pyridine hybrid ligand with copper(I) initially affords its sterically congested, C-2-symmetric stereoisomer, which then undergoes partial isomerisation to a dynamic mixture containing the less crowded meso-configured diastereomer.

引用

页码：280 / 281

页数：2

共 24 条

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[2]

2-3

[3]

[Anonymous], 2002, SPART 02

[4]

Bark T, 2001, ANGEW CHEM INT EDIT, V40, P2848, DOI 10.1002/1521-3773(20010803)40:15<2848::AID-ANIE2848>3.0.CO