Fluorescent solvatochromism of bi-polar N,N-diphenylaminoaryl-substituted hexaazatriphenylenes, tetraazaphenanthrene, and quinoxalines

被引:38
作者
Hirayama, T
Yamasaki, S
Ameku, H
Ishi-i, T
Thiemann, T
Mataka, S
机构
[1] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
[2] Kyushu Sangyo Univ, Dept Ind Chem, Fac Engn, Higashi Ku, Fukuoka 8138503, Japan
[3] Kyushu Univ, Grad Sch Engn Sci, Dept Mol Sci & Technol, Kasuga, Fukuoka 8168580, Japan
关键词
hexaazatriphenylene; tetraazaphenanthrene; solvatochromism; N; N-diphenylamino;
D O I
10.1016/j.dyepig.2004.09.023
中图分类号
O69 [应用化学];
学科分类号
081704 [应用化学];
摘要
1,4,5,8,9,12-Hexaazatriphenylenes, 1,4,5,8-tetraazaphenanthrene, and quinoxalines, each with six, four, and two N,N-diphenylaminobiphenyl and N,N-diphenylaminophenyl groups, respectively, were prepared and their absorption and fluorescent spectral behaviors were investigated. These compounds showed strong fluorescent solvatochromism arising from the donor-acceptor nature of the pi-electron-deficient aromatic core and pi-electron-rich diphenylamino terminal groups. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:105 / 110
页数:6
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