A generally applicable synthetic approach for heteroleptic thiolate complexes of bismuth

被引：12

作者：

Agocs, L ^{[1
]}

Briand, GG ^{[1
]}

Burford, N ^{[1
]}

Eelman, MD ^{[1
]}

Aumeerally, N ^{[1
]}

MacKay, D ^{[1
]}

Robertson, KN ^{[1
]}

Cameron, TS ^{[1
]}

机构：

[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2003年 / 81卷 / 06期

关键词：

bismuth; thiolate; heteroleptic; crystallography;

D O I：

10.1139/V03-054

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As part of a systematic development of bismuth coordination chemistry, we are exploiting the thermodynamic and hydrolytic stability of Bi-S bonds. A series of heteroleptic thiolate bismuth complexes have been isolated and characterized. The generally applicable synthetic methodology involves the use of hetero-bifunctional ligands containing a thiolate moiety as an anchor to facilitate coordinate interaction of weak donors (carbonyls, amines, hydroxyls) with bismuth. The bifunctional nature of the ligands is manifested in chelating roles. Important comparisons with established thiolate complexes of bismuth are discussed.

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收藏

页码：632 / 637

页数：6

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