Bis(1,3,5-triaza-7-phosphaadamantane-P)-gold(I) chloride

被引：20

作者：

Assefa, Z ^{[1
]}

Staples, RJ ^{[1
]}

Fackler, JP ^{[1
]}

机构：

[1] TEXAS A&M UNIV,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷 / pt 2期

关键词：

D O I：

10.1107/S0108270195008183

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The central Au atom in the title compound, [AU(C6H12-N3P)(2)]Cl, lies on an inversion center and the twofold coordination is necessarily linear, with Au-P 2.261 (5) Angstrom. The Cl- ion is in a general position with 0.5 occupancy; the shortest Au ... Cl distance is 3.224 (4) Angstrom.

引用

页码：305 / 307

页数：3

共 16 条

[1] SYNTHESES, CHARACTERIZATIONS, LUMINESCENCE PROPERTIES, AND ELECTRONIC-STRUCTURES OF GOLD(I) BIS(PHOSPHINE)-XANTHATE COMPLEXES [J].

ASSEFA, Z ;

STAPLES, RJ ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1994, 33 (13) :2790-2798

[2] CRYSTAL AND MOLECULAR-STRUCTURE OF CHLOROBIS(TRIPHENYLPHOSPHINE)GOLD(I) HEMIBENZENATE [J].

BAENZIGER, NC ;

DITTEMORE, KM ;

DOYLE, JR .

INORGANIC CHEMISTRY, 1974, 13 (04) :805-811

[3] LEWIS-BASE ADDUCTS OF GROUP-11 METAL(I) COMPOUNDS .27. SOLID-STATE P-31 CROSS-POLARIZATION MAGIC-ANGLE SPINNING NUCLEAR-MAGNETIC-RESONANCE, FAR-INFRARED, AND STRUCTURAL STUDIES ON THE MONONUCLEAR 2-1 ADDUCTS OF TRIPHENYLPHOSPHINE WITH COPPER(I) AND GOLD(I) HALIDES [J].

BOWMAKER, GA ;

DYASON, JC ;

HEALY, PC ;

ENGELHARDT, LM ;

PAKAWATCHAI, C ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (05) :1089-1097

[4] A NEW TYPE OF GOLD CLUSTER COMPOUND. THE SYNTHESES AND X-RAY STRUCTURE-ANALYSIS OF PENTAKIS(TRICYCLOHEXYLPHOSPHINO)TRIS(THIOCYANATO)ENNEAGOLD,[AU9(P(C6H11)3)5(SCN)3], AND BIS(TRI(CYCLOHEXYL)PHOSPHINATO)GOLD(I) HEXAFLUOROPHOSPHATE,[AU(P(C6H11)3)2][PF6] [J].

COOPER, MK ;

DENNIS, GR ;

HENRICK, K ;

MCPARTLIN, M .

INORGANICA CHIMICA ACTA-LETTERS, 1980, 45 (04) :L151-L152

[5] SYNTHESIS AND SPECTRAL PROPERTIES OF METAL-CARBONYL DERIVATIVES OF TETRABASIC, NONCHELATING PHOSPHATRIAZAADAMANTANE LIGAND [J].

DARENSBOURG, MY ;

DAIGLE, D .

INORGANIC CHEMISTRY, 1975, 14 (05) :1217-1218

[6] BIS(TRIETHYLPHOSPHINE)GOLD(I) BIS(1,2-BENZENEDITHIOLATO-S,S')GOLD(III), [AU(P(C2H5)3)(2)][AU(S2C6H4)(2)] [J].

DAVILA, RM ;

STAPLES, RJ ;

FACKLER, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1994, 50 :1898-1900

[7] CRYSTAL-STRUCTURE OF TRIS(TRIPHENYLPHOSPHINE)GOLD(I)-[DODECAHYDRIDO-6-THIA-NIDO-DECABORATE(1-)] [J].

GUGGENBE.LJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 81 (02) :271-280

[8] SYNTHESES AND CHARACTERIZATION OF GOLD(I) AND PLATINUM(II) COMPLEXES CONTAINING TRIS(2-CYANOETHYL)PHOSPHINE - X-RAY CRYSTAL-STRUCTURES OF [(CEP)2AU]CL, CIS-(CEP)(ET2S)PTCL2, AND TRANS-(CEP)2PTCL2 [J].

KHAN, MNI ;

KING, C ;

FACKLER, JP ;

WINPENNY, REP .

INORGANIC CHEMISTRY, 1993, 32 (11) :2502-2505

[9] BIS(TRICYCLOHEXYLPHOSPHINE)GOLD(I) THIOCYANATE [J].

MUIR, JA ;

MUIR, MM ;

LORCA, E .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (APR) :931-933

[10] THIOCYANATOBIS(TRIPHENYLPHOSPHINE)GOLD(I) [J].

MUIR, JA ;

MUIR, MM ;

ARIAS, S .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (APR) :1318-1320

← 1 2 →