Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal-Organic Framework Decorated with Acylamide Groups

被引：701

作者：

Zheng, Baishu ^{[1
]}

Bai, Junfeng ^{[1
]}

Duan, Jingui ^{[1
]}

Wojtas, Lukasz ^{[2
]}

Zaworotko, Michael J. ^{[2
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 04期

关键词：

BUILDING-BLOCKS SBBS; CARBON-DIOXIDE; SEPARATION; METHANE; SEQUESTRATION; CHEMISTRY; HYDROGEN; LINKING; STORAGE; DESIGN;

D O I：

10.1021/ja110042b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An rht-type metal organic framework (MOF) prepared from M-2(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C-3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N-2 in comparison with what was previously observed for an analogous MOF with alkyne groups.

引用

页码：748 / 751

页数：4

共 48 条

[1] High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores
An, Jihyun
Geib, Steven J.
Rosi, Nathaniel L.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) : 38 - +
[2] [Anonymous], 1997, CRC HDB CHEM PHYS
[3] CO2 capture using some fly ash-derived carbon materials
Arenillas, A
Smith, KM
Drage, TC
Snape, CE
[J]. FUEL, 2005, 84 (17) : 2204 - 2210
[4] Amine functionalised metal organic frameworks (MOFs) as adsorbents for carbon dioxide
Arstad, Bjornar
Fjellvag, Helmer
Kongshaug, Kjell Ove
Swang, Ole
Blom, Richard
[J]. ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2008, 14 (06): : 755 - 762
[5] Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks
Bae, Youn-Sang
Mulfort, Karen L.
Frost, Houston
Ryan, Patrick
Punnathanam, Sudeep
Broadbelt, Linda J.
Hupp, Joseph T.
Snurr, Randall Q.
[J]. LANGMUIR, 2008, 24 (16) : 8592 - 8598
[6] A challenge for green chemistry: designing molecules that readily dissolve in carbon dioxide
Beckman, EJ
[J]. CHEMICAL COMMUNICATIONS, 2004, (17) : 1885 - 1888
[7] Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
Britt, David
Furukawa, Hiroyasu
Wang, Bo
Glover, T. Grant
Yaghi, Omar M.
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) : 20637 - 20640
[8] Supermolecular building blocks (SBBs) and crystal design: 12-connected open frameworks based on a molecular cubohemioctahedron
Cairns, Amy J.
Perman, Jason A.
Wojtas, Lukasz
Kravtsov, Victor Ch.
Alkordi, Mohamed H.
Eddaoudi, Mohamed
Zaworotko, Michael J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (05) : 1560 - +
[9] Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13X at high pressures
Cavenati, S
Grande, CA
Rodrigues, AE
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04) : 1095 - 1101
[10] Multiroute Synthesis of Porous Anionic Frameworks and Size-Tunable Extraframework Organic Cation-Controlled Gas Sorption Properties
Chen, Shumei
Zhang, Jian
Wu, Tao
Feng, Pingyun
Bu, Xianhui
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) : 16027 - +

← 1 2 3 4 5 →