Band-gap shift transition in the photoluminescence of single-walled carbon nanotubes

被引:58
作者
Finnie, P
Homma, Y
Lefebvre, J
机构
[1] Natl Res Council Canada, Inst Microstruct Sci, Ottawa, ON K1A 0R6, Canada
[2] NTT Corp, NTT Basic Res Labs, Kanagawa 2430198, Japan
关键词
D O I
10.1103/PhysRevLett.94.247401
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Photoluminescence (PL) from single-walled carbon nanotubes suspended in free space is shown to persist to high temperatures, at least to 425 degrees C. A new transition is identified, shifting the optical band gap. This transition is abrupt, is hysteretic, depends simply on the PL emission energy, and is affected by the gas atmosphere. A model is proposed to explain the transition, connecting changes in the PL to the environment.
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页数:4
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