A rhodamine-based fluorescent and colorimetric chemodosimeter for the rapid detection of Hg2+ ions in aqueous media

被引:1039
作者
Yang, YK
Yook, KJ
Tae, J [1 ]
机构
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[2] Yonsei Univ, Ctr Bioact Mol Hybrids, Seoul 120749, South Korea
关键词
D O I
10.1021/ja054855t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A rhodamine-based fluorescent and colorimetric chemodosimeter for the rapid detection of Hg2+ ions in aqueous media was developed. The system, which utilizes an irreversible Hg2+-promoted oxadiazole forming reaction, responds instantaneously at room temperature in a 1:1 stoichiometric manner to the amount of Hg2+. The selectivity of this system for Hg2+ over other metal ions is remarkably high, and its sensitivity is below 2 ppb in aqueous solutions. Copyright © 2005 American Chemical Society.
引用
收藏
页码:16760 / 16761
页数:2
相关论文
共 34 条
[1]   A colorimetric ligand for mercuric ion [J].
Brummer, O ;
La Clair, JJ ;
Janda, KD .
ORGANIC LETTERS, 1999, 1 (03) :415-418
[2]   FLUOROMETRIC CHEMODOSIMETRY - MERCURY(II) AND SILVER(I) INDICATION IN WATER VIA ENHANCED FLUORESCENCE SIGNALING [J].
CHAE, MY ;
CZARNIK, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) :9704-9705
[3]   A new Hg2+-selective fluorescent sensor based on a dansyl amide-armed calix[4]-aza-crown [J].
Chen, QY ;
Chen, CF .
TETRAHEDRON LETTERS, 2005, 46 (01) :165-168
[4]   A new Hg2+-selective chromoionophore based on calix[4]arenediazacrown ether [J].
Choi, MJ ;
Kim, MY ;
Chang, SK .
CHEMICAL COMMUNICATIONS, 2001, (17) :1664-1665
[5]   Reversible colorimetric probes for mercury sensing [J].
Coronado, E ;
Galán-Mascaros, JR ;
Martí-Gastaldo, C ;
Palomares, E ;
Durrant, JR ;
Vilar, R ;
Gratzel, M ;
Nazeeruddin, MK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) :12351-12356
[6]  
Czarnik A.W., 1993, ACS S SERIES
[7]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[8]   Coupling selectivity with sensitivity in an integrated chemosensor framework:: Design of a Hg2+-responsive probe, operating above 500 nm [J].
Descalzo, AB ;
Martínez-Máñez, R ;
Radeglia, R ;
Rurack, K ;
Soto, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) :3418-3419
[9]   A long-wavelength fluorescent chemodosimeter selective for Cu(II) ion in water [J].
Dujols, V ;
Ford, F ;
Czarnik, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (31) :7386-7387
[10]  
FABBRIZZI L, 1994, ACCOUNTS CHEM RES, V27, P302