Photoelectron spectra of vinyl- and 1-alkynylgermanes and stannanes

被引：16

作者：

Chrostowska, A

Metail, V

Pfister-Guillouzo, G

Guillemin, JC

机构：

[1] Univ Pau & Pays Adour, Grp Physicochim Mol, CNRS, UMR 5624, F-64000 Pau, France

[2] ENSCR, Grp Synth & Activat Biomol, CNRS, UMR 6052, F-35700 Rennes, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 570卷 / 02期

关键词：

photoelectron spectroscopy; vinylgermane; vinylstannane; 1-alkynylgermane; 1-alkynylstannane;

D O I：

10.1016/S0022-328X(98)00718-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Primary vinylic and acetylenic germanes and stannanes, synthesized by a chemoselective reduction of the corresponding trichloro derivatives, were investigated by ab initio quantum chemical methods and photoelectron spectroscopy. In particular, the PE spectra display very well-resolved bands which show the increasing destabilizing effect of 14 group heteroatom cl-substitution of double or triple carbon-carbon bonds. (C) 1998 Elsevier Science S.A. All rights reserved.

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页码：175 / 182

页数：8

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