Crystal engineering studies of the complexes of ethyl resorcinarene with aromatic nitrogen heterocycles

被引：30

作者：

Nissinen, M ^{[1
]}

Rissanen, K ^{[1
]}

机构：

[1] Univ Jyvaskyla, Dept Chem, Jyvaskyla 40014, Finland

来源：

SUPRAMOLECULAR CHEMISTRY | 2003年 / 15卷 / 7-8期

基金：

芬兰科学院;

关键词：

crystal engineering; X-ray diffraction; resorcinarenes; complexation; nitrogen heterocycles;

D O I：

10.1080/10610270310001605179

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five X-ray structures of complexes of ethyl resorcinarene with aromatic nitrogen heterocycles (imidazole, 1,2,4-triazole, pyridine, pyrazine, 2-pyridylmethanol and quinoline) show that ethyl resorcinarene spontaneously forms molecular inclusion complexes with five- and six-membered aromatic nitrogen heterocycles via pi(...)pi and CH(...)pi interactions. However, with 10-membered quinoline, no molecular inclusion complex is formed. Instead, quinoline manifests crystal lattice inclusion.

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页码：581 / +

页数：12

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