Robust thermal performance of Sr2Si5N8:Eu2+: An efficient red emitting phosphor for light emitting diode based white lighting

被引:208
作者
Brinkley, Stuart E. [1 ]
Pfaff, Nathan [2 ]
Denault, Kristin A. [2 ]
Zhang, Zhijun [3 ]
Hintzen, H. T. [3 ]
Seshadri, Ram [1 ,4 ]
Nakamura, Shuji [1 ,2 ]
DenBaars, Steven P. [1 ,2 ]
机构
[1] Univ Calif Santa Barbara, Elect & Comp Engn Dept, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
[3] Tech Univ Eindhoven, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
[4] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
关键词
LUMINESCENCE PROPERTIES; GEOMETRY; SR;
D O I
10.1063/1.3666785
中图分类号
O59 [应用物理学];
学科分类号
摘要
An important component to the advent of solid state lighting technology is the development of inorganic crystalline phosphors for efficient conversion of photons from blue light emitting diodes (LEDs) to other visible wavelengths for greater color rendering and "warmer" white lighting. We present the results of a recently developed rare earth doped nitride-based red emitting phosphor, Sr2Si5N8:Eu2+, combined with GaN-based blue emitting LEDs and YAG:Ce phosphor for improved white lighting applications. A unique remote phosphor packaging approach was used in all testing to isolate LED performance from phosphor performance. Luminous efficacies were achieved at 94 lm/W with an improved color rendering index (CRI) of 72, mixing red phosphor with YAG: Ce. The Sr2Si5N8:Eu2+ red emitting phosphor was found to have a low temperature sensitivity (only 28% power reduction at 150 degrees C) and greater luminous performance at low concentrations in the encapsulant by weight relative to other typical red emitting phosphors. (C) 2011 American Institute of Physics. [doi:10.1063/1.3666785]
引用
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页数:3
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共 17 条
[1]   A nearly ideal phosphor-converted white light-emitting diode [J].
Allen, Steven C. ;
Steckl, Andrew J. .
APPLIED PHYSICS LETTERS, 2008, 92 (14)
[2]   Superior Illuminant Characteristics of Color Rendering and Luminous Efficacy in Multilayered Phosphor Conversion White Light Sources Excited by Near-Ultraviolet Light-Emitting Diodes [J].
Fukui, Takeshi ;
Kamon, Kunihito ;
Takeshita, Junichi ;
Hayashi, Hideki ;
Miyachi, Tsutomu ;
Uchida, Yuji ;
Kurai, Satoshi ;
Taguchi, Tsunemasa .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2009, 48 (11)
[3]   MEASUREMENT OF ABSOLUTE PHOTOLUMINESCENCE QUANTUM EFFICIENCIES IN CONJUGATED POLYMERS [J].
GREENHAM, NC ;
SAMUEL, IDW ;
HAYES, GR ;
PHILLIPS, RT ;
KESSENER, YARR ;
MORATTI, SC ;
HOLMES, AB ;
FRIEND, RH .
CHEMICAL PHYSICS LETTERS, 1995, 241 (1-2) :89-96
[4]   Efficient and Color-Tunable Oxyfluoride Solid Solution Phosphors for Solid-State White Lighting [J].
Im, Won Bin ;
George, Nathan ;
Kurzman, Joshua ;
Brinkley, Stuart ;
Mikhailovsky, Alexander ;
Hu, Jerry ;
Chmelka, Bradley F. ;
DenBaars, Steven P. ;
Seshadri, Ram .
ADVANCED MATERIALS, 2011, 23 (20) :2300-+
[5]   Sr2.975-xBaxCe0.025AlO4F: a Highly Efficient Green-Emitting Oxyfluoride Phosphor for Solid State White Lighting [J].
Im, Won Bin ;
Brinkley, Stuart ;
Hu, Jerry ;
Mikhailovsky, Alexander ;
DenBaars, Steven P. ;
Seshadri, Ram .
CHEMISTRY OF MATERIALS, 2010, 22 (09) :2842-2849
[6]   The effect of replacement of Sr by Ca on the structural and luminescence properties of the red-emitting Sr2Si5N8:Eu2+ LED conversion phosphor [J].
Li, Y. Q. ;
De With, G. ;
Hintzen, H. T. .
JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (03) :515-524
[7]   Luminescence properties of red-emitting M2Si5N8:Eu2+ (M=Ca, Sr, Ba) LED conversion phosphors [J].
Li, Y. Q. ;
van Steen, J. E. J. ;
van Krevel, J. W. H. ;
Botty, G. ;
Delsing, A. C. A. ;
DiSalvo, F. J. ;
de With, G. ;
Hintzen, H. T. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 417 (1-2) :273-279
[8]   Effects of phosphor application geometry on white light-emitting diodes [J].
Masui, Hisashi ;
Nakamura, Shuji ;
DenBaars, Steven P. .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (33-36) :L910-L912
[9]   Highly efficient all-nitride phosphor-converted white light emitting diode [J].
Mueller-Mach, R ;
Mueller, G ;
Krames, MR ;
Höppe, HA ;
Stadler, F ;
Schnick, W ;
Juestel, T ;
Schmidt, P .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2005, 202 (09) :1727-1732
[10]   Phosphors materials and combinations for illumination grade white pcLED [J].
Mueller-Mach, R ;
Mueller, GO ;
Krames, MR .
THIRD INTERNATIONAL CONFERENCE ON SOLID STATE LIGHTING, 2004, 5187 :115-122