From helicate to infinite coordination polymer: crystal and molecular structures of silver(I) complexes of readily prepared di-Schiff bases

被引：127

作者：

Bowyer, PK ^{[1
]}

Porter, KA ^{[1
]}

Rae, AD ^{[1
]}

Willis, AC ^{[1
]}

Wild, SB ^{[1
]}

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 10期

关键词：

D O I：

10.1039/a800083b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The readily prepared di-Schiff base of pyridine-2-aldehyde and ethane-1,2-diamine 1 reacts with silver(I) tetrafluoroborate to form by self-assembly the double-stranded D-2-helicate (+/-)-[Ag(2)1(2)](BF4)(2); the corresponding Schiff base of (1R,2R)-cyclohexane-1,2-diamine [(R,R)-2] reacts with silver(I) nitrate to produce the homochiral single-stranded C-2-coordination polymer M-{[Ag{(R,R)-2}]NO3 . 2H(2)O}(infinity).

引用

页码：1153 / 1154

页数：2

共 17 条

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