Characterisation of LaNi1-xCoxO3 as a possible SOFC cathode material

被引:86
作者
Hrovat, M [1 ]
Katsarakis, N [1 ]
Reichmann, K [1 ]
Bernik, S [1 ]
Kuscer, D [1 ]
Holc, J [1 ]
机构
[1] GRAZ UNIV TECHNOL,INST CHEM TECHNOL INORGAN MAT,A-8010 GRAZ,AUSTRIA
关键词
solid oxide fuel cell (SOFC); cathode; cobalt doping; thick film; electrical measurements; reactivity;
D O I
10.1016/0167-2738(95)00224-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The perovskite with nominal composition LaNi0.6Co0.4O3 was evaluated for the use as a possible solid oxide fuel cell (SOFC) cathode. Thick film layers, printed and fired on yttria stabilised zirconia (YSZ) electrolyte, exhibit good characteristics, i.e. a porous microstructure, a temperature expansion coefficient of 11.9 X 10(-6)/K, and low, temperature independent, sheet resistivity. However, LaNi0.6Co0.4O3 reacts with YSZ at lower temperatures than other perovskites which are usually used for SOFC cathodes.
引用
收藏
页码:99 / 105
页数:7
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