Asymmetric ethylmagnesiation of alkenes using a novel zirconium catalyst

被引：30

作者：

Bell, L

Brookings, DC

Dawson, GJ

Whitby, RJ ^{[1
]}

Raymond, VH

Michael, CH

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[2] Zeneca Proc Technol, Grangemouth FK3 8XG, Stirling, Scotland

来源：

TETRAHEDRON | 1998年 / 54卷 / 48期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4020(98)00920-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The novel C-1-symmetric zirconocene CpCp*ZrCl2 (Cp=C5H5, Cp*=1-neomenthyl-4, 5, 6, 7-tetrahydroindenyl) is a cheap, active, and effective catalyst for the asymmetric ethylmagnesiation of unactivated terminal alkenes. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：14617 / 14634

页数：18

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