The catalytic activity of Co/ZrO2 for NO reduction with propane in O2 presence

被引:4
作者
Lick, ID
Carrascull, A
Ponzi, M
Ponzi, EN
机构
[1] Natl Univ La Plata, CONICET, CINDECA, RA-1900 La Plata, Buenos Aires, Argentina
[2] UNSL, CONICET, INTEQUI, Fac Ingn & Ciencias Econ Sociales, San Luis, Argentina
关键词
NO selective reduction; Co/ZrO2; propane;
D O I
10.1023/A:1025742110405
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The selective catalytic reduction (SCR) of NO by propane in the presence of excess oxygen was studied on a Co=ZrO2 catalyst. This system is present as active for the NO reduction to N-2. It was found that the addition of Co could improve the activity and selectivity of propane towards NOx reduction. The activity depends strongly on the space velocity (GHSV) when the system works with low oxygen concentration and it is independent of the space velocity when the system operates with excess oxygen. The water vapor present in the feed produces deactivation in the catalyst as well as in the support.
引用
收藏
页码:179 / 184
页数:6
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