Interchain interactions in π-conjugated oligomers and polymers:: a primer

被引：39

作者：

Cornil, J

Calbert, JP

Beljonne, D

Silbey, R

Brédas, JL

机构：

[1] Univ Mons, Ctr Rech Elect & Photon Mol, B-7000 Mons, Belgium

[2] MIT, Ctr Mat Sci & Engn, Dept Chem, Cambridge, MA 02139 USA

[3] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA

来源：

SYNTHETIC METALS | 2001年 / 119卷 / 1-3期

关键词：

semi-empirical models; optical absorption and emission spectroscopy; transport measurements; single crystalline thin films;

D O I：

10.1016/S0379-6779(00)00594-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this contribution, we review our recent quantum-chemical studies on intermolecular interactions and the way they impact the transport and optical properties of organic conjugated materials. When applied to the crystalline structures of two prototypical oligomeric materials, alpha -sexithienyl and alpha-alpha ' -bisdithieno[3,2-b:2 ' ,3 ' -d]thiophen our approach illustrates how the variations in chain packing lead to dramatically different optical splittings and carrier mobilities. Various strategies to prevent solid-state luminescence quenching in light-emitting devices are proposed.

引用

页码：1 / 6

页数：6

共 40 条

[1] Interchain interactions in conjugated materials:: The exciton model versus the supermolecular approach [J].