Forming aromatic hemispheres on transition-metal surfaces

被引：65

作者：

Rim, Kwang Taeg

Siaj, Mohamed

Xiao, Shengxiong

Myers, Matthew

Carpentier, Vincent D.

Liu, Li

Su, Chaochin

Steigerwald, Michael L.

Hybertsen, Mark S.

McBreen, Peter H.

Flynn, George W. ^{[1
]}

Nuckolls, Colin

机构：

[1] Columbia Univ, Ctr Electron Transport Mol Nanostruct, Dept Chem, New York, NY 10027 USA

[2] Univ Laval, Dept Chem, Quebec City, PQ G1K 7P4, Canada

[3] Natl Taipe Univ Technol, Dept Mol Sci & Engn, Taipei 106, Taiwan

[4] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期

关键词：

carbon; nanostructures; nanotubes; polycycles; surface chemistry;

D O I：

10.1002/anie.200701117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Bowled over: Hexabenzocoronene (HBC) binds to the surface of a ruthenium crystal through its "radialene" π bonds. Measurements on the product after heating of the HBC-surface complex are consistent with a bowl-shaped molecular fragment that is strongly bound, rim down, to the metal surface. This structure represents a new type of seed that could be used to grow single-walled carbon nanotubes of specific diameter and chirality. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：7891 / 7895

页数：5

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