Crystal structure of the higher fullerene C84

被引：35

作者：

Margadonna, S

Brown, CM

Dennis, TJS

Lappas, A

Pattison, P

Prassides, K ^{[1
]}

Shinohara, H

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

[2] Nagoya Univ, Dept Chem, Nagoya, Aichi 46401, Japan

[3] Univ Lausanne, Inst Cristallog, CH-1015 Lausanne, Switzerland

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 07期

关键词：

D O I：

10.1021/cm980183c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High-resolution synchrotron X-ray powder diffraction is used to study the crystal structure of the higher fullerene C-84 in the temperature range 5-295 K. Solid C-84 (mixture of two molecular isomers, D-2(IV) and D-2d(II) in the ratio 2:1, respectively) adopts a face-centered-cubic (fcc) structure at all temperatures (a = 15.817(4) Angstrom at 20 K).

引用

页码：1742 / +

页数：4

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