Rhodium-mediated silylative cyclization of 1,6-heptadiynes

被引：47

作者：

Muraoka, T ^{[1
]}

Matsuda, I ^{[1
]}

Itoh, K ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Nagoya, Aichi 4648603, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(98)01571-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

RhCl(PPh3)(3) readily reacts with an equivalent mole of a hydrosilane to form the Si-Rh-H species that plays an important role in the silylative cyclization of 1,6-heptadiynes to construct 1,2-dialkylidenecyclopentane derivatives. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7325 / 7328

页数：4

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