Synthesis and characterization of a new gallophosphate (Mu-1) containing cobalticinium cations

被引：36

作者：

Kallus, S

Patarin, J

Marler, B

机构：

[1] UNIV HAUTE ALSACE,ECOLE NATL SUPER CHIM MULHOUSE,LAB MAT MINERAUX,CNRS 428,URA,F-68093 MULHOUSE,FRANCE

[2] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,D-55099 MAINZ,GERMANY

[3] RUHR UNIV BOCHUM,INST MINERAL,D-44780 BOCHUM,GERMANY

来源：

MICROPOROUS MATERIALS | 1996年 / 7卷 / 2-3期

关键词：

cobalticinium cations; gallophosphates; fluoride anions; solid state NMR spectroscopy;

D O I：

10.1016/0927-6513(96)00019-3

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The use of bis(cyclopentadienyl)cobalt(III) ion (Cp(2)Co)(+) in the system Ga2O3-P2O5-HF-H2O was investigated. A new gallophosphate consisting of (Cp(2)Co)(+) cations and Ga4P4O12(OH)(8) D4R units hosting F- anions was obtained. It is structurally closely related to a gallophosphate previously prepared in the presence of dabconium cations. The material was characterized by elemental analysis, SEM, XRD, thermal analysis and solid state NMR spectroscopy.

引用

页码：89 / 95

页数：7

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