A four-oxidation-state family of coordinated carbon:: The first isolable and crystallographically characterized triradical [M]-C4-[M]3+

被引：120

作者：

Guillemot, M

Toupet, L

Lapinte, C

机构：

[1] Univ Rennes 1, CNRS, UMR 6509, F-35042 Rennes, France

[2] Univ Rennes 1, Grp Mat Condensee & Mat, CNRS, UMR 6626, F-35042 Rennes, France

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 10期

关键词：

D O I：

10.1021/om980179a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The deep blue complex [Cp*(dippe)Fe(mu-C-4)-Fe(dippe)Cp*](3+)[PF6](-)(3) (4(3+)[PF6](-)(3)) was prepared by a cascade of three successive one-electron oxidations of the neutral complex Cp*(dippe)Fe(mu-C-4)Fe(dippe)Cp* (4). This unprecedented trication was characterized by X-ray methods, and its triradical structure was established on the basis of Mossbauer, near-IR, and ESR spectroscopy.

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页码：1928 / 1930

页数：3

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