Determination of uric acid by voltammetry and coulometric titration

被引:17
作者
Abdullin, IF [1 ]
Bakanina, YN [1 ]
Turova, EN [1 ]
Budnikov, GK [1 ]
机构
[1] Kazan State Univ, Dept Chem, Kazan 420008, Russia
关键词
D O I
10.1023/A:1016631104353
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Possible mechanisms of the electrochemical oxidation of uric acid at platinum, gold, graphite, and copper electrodes in a 0.5 M NaOH solution and phosphate (pH 6.86) acid berate (pH 9.18) buffer solutions were considered. The stoichiometric coefficients in the reaction of boric acid with electrogenerated bromine and hypobromite ion were determined. Working conditions for the voltammetric determination of uric acid were selected and the detection limits for uric acid were found in model solutions and blood serum.
引用
收藏
页码:453 / 456
页数:4
相关论文
共 9 条
[1]   Ascorbate prevents prooxidant effects of urate in oxidation of human low density lipoprotein [J].
Abuja, PM .
FEBS LETTERS, 1999, 446 (2-3) :305-308
[2]  
BALAKHOVSKII SD, 1953, METODY KHIMICHESKOGO, P407
[3]  
BEREZOVA TT, 1976, RUKOVODSTVO LABORATO, P6
[4]  
Gong ZL, 1996, ANAL LETT, V29, P695
[5]  
MELENTEVA GA, 1976, FARMATSEVTICHESKAYA, P562
[6]   Effect of uric acid and chemical analogues on oxidation of human low density lipoprotein in vitro [J].
Schlotte, V ;
Sevanian, A ;
Hochstein, P ;
Weithmann, KU .
FREE RADICAL BIOLOGY AND MEDICINE, 1998, 25 (07) :839-847
[7]  
TOMILOV AP, 1968, ELEKTROKHIMIYA ORGAN, P332
[8]   A rapid gas chromatographic assay for determining oxyradical scavenging capacity of antioxidants and biological fluids [J].
Winston, GW ;
Regoli, F ;
Dugas, AJ ;
Fong, JH ;
Blanchard, KA .
FREE RADICAL BIOLOGY AND MEDICINE, 1998, 24 (03) :480-493
[9]   Catalytic oxidation of uric acid at the polyglycine chemically modified electrode and its trace determination [J].
Yu, AM ;
Zhang, HI ;
Chen, HY .
ANALYST, 1997, 122 (08) :839-841