Atom-transfer reactions catalyzed by methyltrioxorhenium(VII) - mechanisms and applications

被引：155

作者：

Espenson, JH ^{[1
]}

机构：

[1] Iowa State Univ Sci & Technol, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 06期

关键词：

D O I：

10.1039/a809222b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methyltrioxorhenium activates hydrogen peroxide by an electrophilic mechanism, transferring a single oxygen atom to many substrates without the intervention of free-radical intermediates. The reactions proceed without by-products, unlike those of most chemical (stoichiometric) oxidizing agents. In separate chemistry, the rhenium catalyst brings about the transfer of oxygen atoms between a pair of closed-shell molecules.

引用

页码：479 / 488

页数：10

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