Rearrangement of carbiminium carbonylmetalates by mutual exchange of alkoxy- and amino functionalities (M = W, Cr) -: Crystal structure analyses

被引：6

作者：

Aumann, R ^{[1
]}

Roths, K ^{[1
]}

Fröhlich, R ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 617卷 / 01期

关键词：

carbene complexes; metallahexatrienes; carbiminium carbonylmetalates; chromium and tungsten complexes; enamines;

D O I：

10.1016/S0022-328X(00)00602-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (1-alkynyl)carbene complexes (CO)(5)M=C(OEt)C=CPh (1a,b) (M = Cr, W) with enamines R'(R2N)C=CHR " (4a-d) (R2N = morpholine) yielded carbiminium carbonylmetalates (-)(OC)(5)M-C(OEt)=C[C(=N+R2)R']C(Ph)=CHR " (5) by metathesis of the (N)C=C at the C=C bond. Compounds 5 are stable in solid state, but in solution they undergo a mutual exchange of the ethoxy- and the amino functionality to give isomers (-)(OC)(5)M-C(=N+R2)]C[=C(OEt)R']C(Ph)=CHR " (6), (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：322 / 328

页数：7

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