Charge-transfer complex and radical cation salt of a new donor EDT-TTFCl2: Unique conductivities and crystal structures

被引:27
作者
Iyoda, M [1 ]
Suzuki, H [1 ]
Sasaki, S [1 ]
Yoshino, H [1 ]
Kikuchi, K [1 ]
Saito, K [1 ]
Ikemoto, I [1 ]
Matsuyama, H [1 ]
Mori, T [1 ]
机构
[1] TOKYO INST TECHNOL,DEPT ORGAN & POLYMER MAT,TOKYO 152,JAPAN
关键词
D O I
10.1039/jm9960600501
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
X-Ray structural analyses of the charge-transfer complex (EDT-TTFCl2)(2) . TCNQF(4), 2, and the radical cation salt EDT-TTFCl2 . ClO4, 3, revealed an interesting effect of chlorine substitution on the crystal stacking mode; the electrical conductivity of 2 is unusually high, although it has a mixed-stacking structure.
引用
收藏
页码:501 / 503
页数:3
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