Transition-metal complexes containing trans-spanning diphosphine ligands

被引：138

作者：

Bessel, CA ^{[1
]}

Aggarwal, P

Marschilok, AC

Takeuchi, KJ

机构：

[1] Villanova Univ, Dept Chem, Villanova, PA 19085 USA

[2] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 04期

关键词：

D O I：

10.1021/cr990346w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transition metal complexes containing trans-spanning diphosphine ligands were analyzed. The ligand positions in trans-spanning tertiary phosphine ligands can be sterically crowded or sheltered and the trans-spanning linkages can be modified. To fully realize the reactive potential of transition-metal complexes that contain trans-spanning tertiary phosphine ligands, it is necessary to develop ligands where isomerization is reduced.

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页码：1031 / 1066

页数：36

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