Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

被引：1563

作者：

Satoh, Tetsuya ^{[1
]}

Miura, Masahiro ^{[1
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 37期

关键词：

C-H activation; fused-ring systems; homogeneous catalysis; oxidative coupling; rhodium; C-H BOND; CARBON-HYDROGEN BONDS; INTERNAL ALKYNES; INTERMOLECULAR HYDROACYLATION; CARBOXYLIC-ACIDS; DIRECT ARYLATION; BENZOIC-ACIDS; ARYL HALIDES; DECARBOXYLATIVE PALLADATION; HOMOGENEOUS CATALYSTS;

D O I：

10.1002/chem.201001363

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatic substrates with oxygen- and nitrogen-containing substituents undergo oxidative coupling with alkynes and alkenes under rhodium catalysis through regioselective C-H bond cleavage. Coordination of the substituents to the rhodium center is the key to activate the C-H bonds effectively. Various fused-ring systems can be constructed through these reactions.

引用

页码：11212 / 11222

页数：11

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