A solvothermal synthesis of a novel 1D ladder-like (NH3CH2CH2NH3)AgAsS4 containing N-H•••S hydrogen bonding

被引：27

作者：

An, YL ^{[1
]}

Li, XF ^{[1
]}

Liu, X ^{[1
]}

Ji, M ^{[1
]}

Jia, CY ^{[1
]}

机构：

[1] Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

基金：

中国国家自然科学基金;

关键词：

solvothermal synthesis; quaternary thioarsenate; chain structure;

D O I：

10.1016/S1387-7003(03)00212-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A one-dimensional compound (NH3CH2CH2NH3)AgAsS4 with ladder-like chains was synthesized solvothermally. This compound crystallizes in the monoclinic system, space group C2/c, with a = 13.5805(8) Angstrom, b = 6.5331(3) Angstrom, c = 22.7711(9) Angstrom, alpha = 90degrees, beta= 106.42(3)degrees, gamma = 90degrees, Z = 8. The rare type hydrogen bonding of N-H...S and electrostatic force hold the anionic chains together. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：1137 / 1139

页数：3

共 17 条

[1]

AN Y, IN PRESS INORG CHEM

[2] SYNTHESIS AND CRYSTAL-STRUCTURE DETERMINATION OF (NH4)AG2ASS4, A FURTHER CHALCOPYRITE-TYPE COMPOUND [J].

AUERNHAMMER, M ;

EFFENBERGER, H ;

IRRAN, E ;

PERTLIK, F ;

ROSENSTINGL, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1993, 106 (02) :421-426

[3]

BAIYIN M, IN PRESS CHEM J CHIN

[4] Synthesis and characterization of (Ph(4)P)(2)[Ni2As4S8], (Me(4)N)(2)[Mo2O2As2S7], and (Et(4)N)(2)[Mo2O2As2Se7], new one-dimensional polymeric compounds containing thio- and selenoarsenate ligands [J].

Chou, JH ;

Hanko, JA ;

Kanatzidis, MG .

INORGANIC CHEMISTRY, 1997, 36 (01) :4-9

[5] HYDROTHERMAL ASSEMBLY OF NOVEL COVALENT, EXTENDED STRUCTURES BASED ON [ASXSY]N- BUILDING-BLOCKS DERIVED FROM CONDENSATION OF ASS33- - ISOLATION OF (PH4P)2[INAS3S7] AND (ME4N)2RB[BIAS6S12] [J].

CHOU, JH ;

KANATZIDIS, MG .

INORGANIC CHEMISTRY, 1994, 33 (06) :1001-1002

[6] HYDROTHERMAL SYNTHESIS OF (PH(4)P)(2)[HG2AS4S9] AND (ME(4)N)[HGAS3S6] - EXTENDED CHAINS AND LAYERS BASED ON THE CONDENSATION OF [ASS3](3-) UNITS [J].

CHOU, JH ;

KANATZIDIS, MG .

CHEMISTRY OF MATERIALS, 1995, 7 (01) :5-8

[7] CRYSTAL-STRUCTURE OF LOW-TEMPERATURE GES2 [J].

DITTMAR, G ;

SCHAFER, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (APR15) :1188-1192

[8] CRYSTAL-STRUCTURE OF HT-GES2 [J].

DITTMAR, G ;

SCHAFER, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (AUG15) :2060-&

[9]

Higashi T, 1995, PROGRAM ABSORPTION C

[10] SYNTHESIS OF NEW LOW-DIMENSIONAL QUATERNARY COMPOUNDS, KCU2ASS3 AND KCU4ASS4, IN SUPERCRITICAL AMINE SOLVENT - ALKALI-METAL DERIVATIVES OF SULFOSALTS [J].

JEROME, JE ;

WOOD, PT ;

PENNINGTON, WT ;

KOLIS, JW .

INORGANIC CHEMISTRY, 1994, 33 (09) :1733-1734

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