Reactions of oxo- and peroxo-molybdenum complexes with B(C6F5)3:: crystal structures of cis-[MoO{OB(C6F5)3}(η2-ONEt2)2] and cis-[MoO{OB(C6F5)3}{η2-PhN(O)C(O)Ph}2]

被引：28

作者：

Doerrer, LH

Galsworthy, JR

Green, MLH

Leech, MA

Muller, M

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Chem Crystallog Lab, Oxford OX1 3PD, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 19期

关键词：

D O I：

10.1039/a803126f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxometal complexes [MoO2(eta(2)-O-NR2)(2)], R = Et or CH2Ph, reacted with the strong Lewis acid B(C6F5)(3) at their oxo functionality to give cis-[MoO{OB(C6F5)(3)} (eta(2)-ONR2)(2)], (R = Et 1 or CH2Ph 2). Reaction of the peroxo complex [MoO(O-2){eta(2)-PhN(O)C(O)Ph}(2)] with the same Lewis acid led initially to the formation of [MoO(O-2){B(C6F5)(3)} {eta(2)-PhN(O)C(O)Ph}(2)] 3, which decomposes to form [MoO{OB(C6F5)(3)}{eta(2)-PhN(O)C(O)Ph}(2)] 4. Compounds 1 and 4 have been characterised by X-ray crystallography.

引用

页码：3191 / 3194

页数：4

共 27 条

[1]

[Anonymous], 1992, INT TABLES CRYSTALLO, VC

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