Conductive elastomeric foams prepared by in situ vapor phase polymerization of pyrrole and copolymerization of pyrrole and N-methylpyrrole

被引:45
作者
Fu, YP
Weiss, RA [1 ]
Gan, PP
Bessette, MD
机构
[1] Univ Connecticut, Polymer Sci Program, Storrs, CT 06269 USA
[2] Univ Connecticut, Dept Chem Engn, Storrs, CT 06269 USA
[3] Rogers Corp, Rogers, CT 06263 USA
关键词
D O I
10.1002/pen.10251
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Electrically conductive elastomer foams were prepared by in situ vapor phase copolymerization of pyrrole and N-methylpyrrole within preformed polyurethane foams. The conductive polymer is formed within the dense polymer phase of the foam, and the conductivity of the composite foam ranged from 10(-1) to 10(-7) S/cm. The conductivity depended on the density of the foam, the amount of conducting polymer incorporated, and the copolymer composition. Replacing pyrrole with N-methylpyrrole in the copolymer lowered the conductivity.
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页码:857 / 862
页数:6
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