Anionic versus photochemical diastereoselective deconjugation of diacetone D-glucose α,β-unsaturated esters

被引：16

作者：

Bargiggia, F ^{[1
]}

Piva, O ^{[1
]}

机构：

[1] Univ Lyon 1, UMR CNRS 5622, Lab Chim Organ Photochim & Synth, F-69622 Villeurbanne, France

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 13期

关键词：

D O I：

10.1016/S0957-4166(03)00365-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Deconjugation of diacetone D-glucose alpha, beta-unsaturated esters has been conducted by deprotonation using NaHMDS with HMPA as co-solvent followed by stereoselective protonation at low temperature. High selectivities (>95%) were obtained with oc-methyl linear compounds. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1819 / 1827

页数：9

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