Sol-gel reaction of porphyrin-based superstructures in the organogel phase: Creation of mechanically reinforced porphyrin hybrids

被引：77

作者：

Kishida, T ^{[1
]}

Fujita, N ^{[1
]}

Sada, K ^{[1
]}

Shinkai, S ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 20期

关键词：

D O I：

10.1021/ja050563g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have demonstrated that a one-dimensional molecular assembly created by an H-aggregated porphyrin·Cu(II) stack can be immobilized, without a morphological change, by sol-gel polycondensation of the peripheral triethoxysilyl groups. The resultant gel prepared according to this flowchart has gained a very high thermal stability as well as a unique mechanical strength. Copyright © 2005 American Chemical Society.

引用

页码：7298 / 7299

页数：2

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