Measurements of vapor pressures of aqueous amino acid solutions and determination of activity coefficients of amino acids

被引:64
作者
Kuramochi, H [1 ]
Noritomi, H [1 ]
Hoshino, D [1 ]
Nagahama, K [1 ]
机构
[1] TOKYO METROPOLITAN UNIV,DEPT IND CHEM,HACHIOJI,TOKYO 19203,JAPAN
关键词
D O I
10.1021/je960113r
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor pressures of aqueous solutions of L-amino acids (glycine, L-alanine, L-valine, and L-serine) were measured at various concentrations at 298 K by a differential pressure static method. Activities and activity coefficients of water were determined. The activity coefficients of the amino acids in water were obtained from the activity coefficients of water using the UNIQUAC equation. The obtained activity coefficients of the amino acids were evaluated by comparison of the values obtained by a conventional virial expansion method and the literature data.
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收藏
页码:470 / 474
页数:5
相关论文
共 9 条
[1]   STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].
ABRAMS, DS ;
PRAUSNITZ, JM .
AICHE JOURNAL, 1975, 21 (01) :116-128
[2]  
[Anonymous], 1984, NBS/NRC Steam Tables: Thermodynamic and Transport Properties and Computer Programs for Vapor and Liquid States of Water in SI Units
[3]  
BONDI A, 1965, PHYSICAL PROPERTIES, pCH14
[4]  
COLIN E, 1985, J PHYS CHEM REF DATA, V14, P489, DOI DOI 10.1063/1.555730
[5]  
ELLERTON HD, 1964, J PHYS CHEM, V68
[6]  
HUTCHENS JO, 1963, J BIOL CHEM, V238, P1419
[7]  
LEWIS GN, 1961, THERMODYNAMICS, pCH20
[8]   THERMODYNAMIC PROPERTIES OF AQUEOUS-ELECTROLYTE SOLUTIONS .1. VAPOR-PRESSURE OF AQUEOUS-SOLUTIONS OF LICL, LIBR, AND LII [J].
PATIL, KR ;
TRIPATHI, AD ;
PATHAK, G ;
KATTI, SS .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1990, 35 (02) :166-168
[9]  
ROBINSON RA, 1965, ELECTROLYTE SOLUTION, pCH22